Bis(μ-2,2′-bipyridin-6-olato)-κ3 N, N′: O;κ3 O: N′,N′-dicopper(I, II) dichlorocuprate(II)

被引：5
|
作者：
Guo, Hong-Xu [1 ]
Rao, Zhi-Ming [1 ]
Wang, Qing-Hua [1 ]
机构：
[1] Zhangzhou Normal Univ, Dept Chem & Environm Sci, Fujian 363000, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536806050720
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Cu-2(C10H7N2O)(2)][CuCl2], is formulated as containing a mixed-oxidation-state [Cu-2(obpy)(2)](+) cation (Hobpy is 2,2'-bipyridin-6-ol) and a [CuCl2](-) anion, both of which lie on inversion centres. The mixed-valence Cu-I,Cu-II is coordinated by one O and two N atoms of two obpy ligands. The Cu center dot center dot center dot Cu interaction [2.3805 (9) angstrom] results in a square-planar environment for the Cu-I,Cu-II atoms. The Cu-II atom in the anion is coordinated by two chloride ions in a linear geometry.
引用
收藏
页码：M637 / M638
页数：2
相关论文
共 50 条
  • [1] catena-Poly[bis(μ-2,2′-bipyridin-6-olato)-κ3N,N′:O;O:N,N′-dicopper(I,II) [[tetrafluoridoniobium(V)]-μ-oxido]]
    Zhong, Zhi-Guo
    Feng, Yu-Quan
    Zhang, Ping
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2013, 69 : 833 - 836
  • [2] Bis{μ-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dicopper(II) N,N′-dimethylformamide disolvate
    Yu, Guofeng
    Ding, Yu
    Wang, Li
    Fu, Zhengbing
    Hu, Xinliang
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M504 - U668
  • [3] Bis(3,5-dimethylpyrazole-N2)(2,2-dimethyl-N-salicylideneglycinato-O,N,O′)copper(II)
    Warda, SA
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 916 - 918
  • [4] catena-Poly[[lead(II)-bis(μ2-quinolin-8-olato)-κ3N,O:O;κ3O:N,O] N,N-dimethylformamide hemisolvate]
    Ghaemi, Akbar
    Dadkhah, Zohreh
    Ng, Seik Weng
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : M210 - U1171
  • [5] Bis(μ-2-methylquinolin-8-olato)-κ3N,O:O;κ3O:N,O-bis[(acetato-κ2O,O′)lead(II)]
    Sh, Gholamhossein Mohammadnezhad
    Amini, Mostafa M.
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M260 - U319
  • [6] {μ-N,N′-Bis[2-(dimethylamino)ethyl]oxamidato(2-)-κ6N,N′,O′:N",N"′,O}bis[(2,2′-bipyridine-κ2N,N′)copper(II)] bis(perchlorate)
    Sun, Wei
    Li, Yan-Tuan
    Wu, Zhi-Yong
    Zhang, Shu-Fang
    Yin, Zhi-Wei
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2008, 64 (03) : M108 - M110
  • [7] Crystal Structure of [Bis(N,N,N′,N′-tetramethylethylenediamine)-O,O′-μ-O,O′-oxalato]dihydroxy Dicopper(II)
    Tuncer HöKelek
    Canan ÜNaleroğlu
    Yüksel Mert
    Analytical Sciences, 2000, 16 : 1235 - 1236
  • [8] Crystal structure of [bis(N,N,N′,N′-tetramethylethylenediamine)-O,O′-μ-O,O′-oxalato]dihydroxy dicopper(II)
    Hökelek, T
    Ünaleroglu, C
    Mert, Y
    ANALYTICAL SCIENCES, 2000, 16 (11) : 1235 - 1236
  • [9] Bis(μ-1,10-phenanthrolin-2-olato-κ3N,N′:O)dicopper(I)(Cu-Cu) monohydrate
    Lu, LP
    Feng, SS
    Zhang, HM
    Zhu, ML
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 (06): : M283 - M284
  • [10] Bis[(dihydrogen pyrophosphato-κ2O,O′)(2,2′:6′,2"-terpyridine-κ3 N,N′,N")copper(II)] 4.5-hydrate
    Perec, Mireille
    Baggio, Ricardo
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2011, 67 : M140 - M144
12345