Site-Selective Carbene-Induced C-H Functionalization Catalyzed by Dirhodium Tetrakis(triarylcyclopropanecarboxylate) Complexes

被引：42

作者：

Liao, Kuangbiao ^{[1
]}

Liu, Wenbin ^{[1
]}

Niemeyer, Zachary L. ^{[2
]}

Ren, Zhi ^{[1
]}

Bacsa, John ^{[1
]}

Musaev, Djamaladdin G. ^{[1
,3
]}

Sigman, Mathew S. ^{[2
]}

Davies, Huw M. L. ^{[1
]}

机构：

[1] Emory Univ, Dept Chem, 1515 Dickey Dr, Atlanta, GA 30322 USA

[2] Univ Utah, Dept Chem, 315 South,1400 East, Salt Lake City, UT 84112 USA

[3] Emory Univ, Cherry L Emerson Ctr Sci Computat, 1521 Dickey Dr, Atlanta, GA 30322 USA

来源：

ACS CATALYSIS | 2018年 / 8卷 / 01期

基金：

美国国家科学基金会;

关键词：

site-selectivity; non-activated C-H bond; enantioselective C-H functionalization; donor/acceptor carbene; dirhodium tetracarboxylate; predictive modeling; ACTIVATION; AMINATION; BONDS; TOOLS;

D O I：

10.1021/acscatal.7b03421

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Three types of dirhodium tetrakis(triarylcyclopropanecarboxylate) complexes were generated and shown to adopt disparate high symmetry structures. These catalysts were evaluated in the intermolecular C-H functionalization of an array of terminally substituted n-alkanes and displayed various site-selectivity as a function of catalyst and substrate structure, which could be correlated through quantitative relationships.

引用

页码：678 / 682

页数：5

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