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Volumetric and viscometric studies of binary and ternary miixtures of o-nitrotoluene with methyl alcohol, benzene, toluene, carbon tetrachloride and 1,4-dioxane at 298.15 K
被引:0
|作者:
Rathore, Poonam
[1
]
Singh, Mukhtar
[1
]
机构:
[1] Agra Coll, Dept Chem, Agra 282002, Uttar Pradesh, India
关键词:
thermodynamic functions;
ternary mixtures;
binary mixtures;
viscosity;
D O I:
暂无
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Densities and viscosities of binary and ternary mixtures of o-nitrotoluene with methyl alcohol, benzene, toluene, carbon tetrachloride and 1,4-dioxane have been determined at 298.15 K over the whole composition range. Front density and viscosity data, viscosity deviations (Delta eta) and excess thermodynamic functions, viz. the molar volume (V-E) and the excess Gibbs free energy of activation of viscous flow (Delta G(#E)) have been calculated in respect of binary and tertiary liquid mixtures at 298.15 K and fitted by Redlich-Kister and Cibulka equations respectively. Front the small magnitude of the values of standard deviation it is concluded that the experimental values of Delta eta, V-E and Delta G(#E) compare fairly well with the corresponding theoretical values predicted by Redlich-Kister and Cibulka equations for binary, and tertiary mixtures respectively.
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页码:59 / 68
页数:10
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