Studies on corrosion-inhibiting performance of antithyroid drugs on mild steel in hydrochloric acid

被引：10

作者：

Hoseinpoor, M. ^{[1
]}

Davoodi, A. ^{[2
]}

机构：

[1] Ferdowsi Univ Mashhad, Mat & Met Engn Dept, Fac Engn, Mashhad 917751111, Iran

[2] Hakim Sabzevari Univ, Mat & Polymer Engn Dept, Sabzevar, Iran

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2015年 / 41卷 / 07期

关键词：

Mild steel; Acid inhibition; Antithyroid drugs; Polarisation; Quantum chemical; BENZOTRIAZOLE; DERIVATIVES;

D O I：

10.1007/s11164-013-1527-z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The inhibitive performance of methimazole (MMI) and propylthiouracil (PTU), two antithyroid drugs on corrosion behaviour of mild steel in 0.1 M HCl solution, was investigated by means of electrochemical techniques and quantum chemical analysis. The increase in concentration shows a positive effect on inhibition efficiency while increase in temperature increases and decreases the efficiency of MMI and PTU, respectively. Inhibitor molecules directly adsorb at the surface on the basis of donor-acceptor interactions between the pi-electrons, sulfur and oxygen atoms and the vacant d-orbitals of iron atoms. According to the thermodynamic parameters, MMI and PTU adsorb chemically and physically, respectively. Adsorption of them on metal surfaces follows the Langmuir adsorption isotherm.

引用

页码：4255 / 4272

页数：18

共 50 条

[41] Pyrazole Derivative as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Medium: Electrochemical and Theoretical Studies
Aoufir, El Y.
Lgaz, H.
Toumiat, K.
Salghi, R.
Jodeh, S.
Zougagh, M.
Guenbour, A.
Oudda, H.
RESEARCH JOURNAL OF PHARMACEUTICAL BIOLOGICAL AND CHEMICAL SCIENCES, 2016, 7 (05): : 1219 - 1227
[42] Experimental and theoretical studies on corrosion inhibition of mild steel in hydrochloric acid by thiosemicarbazone of Schiff bases
Yadav, M.
Behera, D.
Kumar, S.
CANADIAN METALLURGICAL QUARTERLY, 2014, 53 (02) : 220 - 231
[43] The Penicillin Derivatives as Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Solution: Experimental and Theoretical Studies
Liang, Yi
Wang, Cheng
Li, JianSheng
Wang, LianJun
Fu, JiaJun
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2015, 10 (10): : 8072 - 8086
[44] Experimental studies on the inhibition performances of isatine Schiff base for the corrosion of mild steel in hydrochloric acid
Al-Amiery, Ahmed
Shaker, Lina M.
Betti, Nadia
MATERIALS TODAY-PROCEEDINGS, 2022, 56 : 2209 - 2212
[45] Temperature Performance of a Thione Quinoxaline Compound as Mild Steel Corrosion Inhibitor in Hydrochloric Acid Medium
El-Hajjaji, F.
Belkhmima, R. A.
Zerga, B.
Sfaira, M.
Taleb, M.
Touhami, M. Ebn
Hammouti, B.
Al-Deyaband, S. S.
Ebenso, Eno
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2014, 9 (09): : 4721 - 4731
[46] Inhibition of mild steel corrosion in presence of fatty acid imidazolines in hydrochloric acid
M. A. Quaraishi
M. Z. A. Rafiquee
Nidhi Saxena
Sadaf Khan
Protection of Metals, 2008, 44 (1): : 91 - 98
[47] Corrosion Inhibition of Mild Steel in Hydrochloric Acid Solution by Amino Acid Complexes
Kiruthikajothi, K.
Chandramohan, G.
ORIENTAL JOURNAL OF CHEMISTRY, 2015, 31 (03) : 1351 - 1354
[48] Inhibition of mild steel corrosion in presence of fatty acid imidazolines in hydrochloric acid
Quraishi, M. A.
Rafiquee, M. Z. A.
Saxena, Nidhi
Khan, Sadaf
PROTECTION OF METALS, 2008, 44 (01): : 91 - 98
[49] Fatty acid thiosemicarbazides as corrosion inhibitors for mild steel in hydrochloric acid solution
Department of Applied Chemistry, Corrosion Research Laboratory, Faculty of Engineering and Technology, Aligarh Muslim University, Aligarh-202 002, India
J. Corros. Sci. Eng., 2006,
[50] Corrosion inhibition of mild steel in hydrochloric acid by 6-aminohexanoic acid
Abdeli, M.
Ahmadi, N. P.
Khosroshahi, R. A.
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION, 2010, 61 (02): : 147 - 151

← 1 2 3 4 5 →