(4R)-4-(Biphenyl-4-yl)-7-chloro-1,2,3,4-tetrahydroquinoline

被引：0
|
作者：
Theissmann, Thomas [2 ]
Bolte, Michael [1 ]
机构：
[1] Goethe Univ Frankfurt, Inst Anorgan Chem, D-60438 Frankfurt, Germany
[2] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
HYDROGENATION;
D O I：
10.1107/S160053681103830X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, C21H18ClN, was synthesized by an enantioselective Bronsted acid-catalysed transfer hydrogenation reaction. The six-membered heterocycle adopts a half-chair conformation. It has the biphenyl residue in an axial position. The two rings of the biphenyl residue are almost coplanar [dihedral angle = 2.65 (9)degrees]. The crystal packing is stabilized by N-H center dot center dot center dot Cl hydrogen bonds, which connect the molecules into chains running along the a axis.
引用
收藏
页码：O2747 / +
页数：10
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