Silica-assisted Suzuki-Miyaura reactions of heteroaryl bromides in aqueous media

被引：53
|
作者：
Shi, Shengyin [1 ]
Zhang, Yuhong [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
来源：
GREEN CHEMISTRY | 2008年 / 10卷 / 08期
关键词：
D O I：
10.1039/b803917h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new palladium catalysis system has been developed for the Suzuki-Miyaura cross-coupling reactions of heteroaryl bromides in aqueous media. The method allows the preparation of a variety of heterobiaryls in good to excellent yields under mild reaction conditions without the use of phosphine ligands. Silica gel is found to be crucial to the successful performance of the reactions and the catalytic system can be reused eighteen times with high efficiency.
引用
收藏
页码：868 / 872
页数：5
相关论文
共 50 条
  • [31] Palladium Supported on Commercial Fumed Silica as Sustainable Catalyst for Suzuki-Miyaura Coupling Reactions
    Kang, Zhen-Wei
    Gao, Zhan-Chen
    Lv, Su-Fang
    Zhang, Fei-Bao
    Jiang, Jian-Xiong
    SILICON, 2019, 11 (01) : 287 - 292
  • [32] One-pot synthesis of chromenes by Suzuki-Miyaura cross-coupling reactions with benzyl bromides
    Ahmed, Atiur
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2019, 96 (11) : 1429 - 1432
  • [33] Palladium Supported on Commercial Fumed Silica as Sustainable Catalyst for Suzuki-Miyaura Coupling Reactions
    Zhen-Wei Kang
    Zhan-Chen Gao
    Su-Fang Lv
    Fei-Bao Zhang
    Jian-Xiong Jiang
    Silicon, 2019, 11 : 287 - 292
  • [34] A supramolecular recyclable catalyst for aqueous Suzuki-Miyaura coupling
    Qi, Miao
    Tan, Pei Zi
    Xue, Fei
    Malhi, Haripal Singh
    Zhang, Zhong-Xing
    Young, David J.
    Hor, T. S. Andy
    RSC ADVANCES, 2015, 5 (05): : 3590 - 3596
  • [35] An expeditious aqueous Suzuki-Miyaura method for the arylation of bromophenols
    Freundlich, Joel S.
    Landis, Howard E.
    TETRAHEDRON LETTERS, 2006, 47 (25) : 4275 - 4279
  • [36] Expanding the scope of the Cu assisted Suzuki-Miyaura reaction
    Crowley, Brendan M.
    Potteiger, Craig M.
    Deng, James Z.
    Prier, Christopher K.
    Paone, Daniel V.
    Burgey, Christopher S.
    TETRAHEDRON LETTERS, 2011, 52 (39) : 5055 - 5059
  • [37] Palladium-catalyzed Suzuki-Miyaura reactions of potassium aryl- and heteroaryltrifluoroborates with aryl- and heteroaryl triflates
    Molander, GA
    Petrillo, DE
    Landzberg, NR
    Rohanna, JC
    Biolatto, B
    SYNLETT, 2005, (11) : 1763 - 1766
  • [38] Microwave-assisted synthesis of phenylpyrimidine derivatives via Suzuki-Miyaura reactions in water
    Le, Yi
    Zhang, Yan
    Wang, Qin
    Rao, Nian
    Li, Dan
    Liu, Li
    Ouyang, Guiping
    Yan, Longjia
    TETRAHEDRON LETTERS, 2021, 68
  • [39] An unsymmetrical Schiff-base derived recyclable Pd-catalyst for Suzuki-Miyaura and Sonogashira reactions in aqueous media
    Puzari, Amlan
    Gogoi, Achinta
    Das, Pankaj
    JOURNAL OF CHEMICAL SCIENCES, 2021, 133 (02)
  • [40] Supported phosphine-free palladium catalysts for the Suzuki-Miyaura reaction in aqueous media
    Phan, Nam T. S.
    Styring, Peter
    GREEN CHEMISTRY, 2008, 10 (10) : 1055 - 1060
12345