Recent Advances in Ni-Catalyzed Allylic Substitution Reactions

被引：34
|
作者：
Zhang, Huijun [1 ]
Gu, Qing [2 ]
You, Shuli [1 ,2 ]
机构：
[1] East China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 39卷 / 01期
基金：
中国国家自然科学基金;
关键词：
allylic substitution; asymmetric catalysis; nickel; transition metal; CROSS-COUPLING REACTION; ACTIVE METHYLENE-COMPOUNDS; DIRECT ALPHA-ALLYLATION; TRANSITION-METAL; BOND FORMATION; C-C; OXIDATIVE ADDITION; GRIGNARD-REAGENTS; NICKEL-COMPLEXES; SIMPLE ALKENES;
D O I：
10.6023/cjoc201809037
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Transition-metal catalyzed allylic substitution reaction is an important approach for constructing carbon-carbon bond and carbon-heteroatom bond. Due to its cheapness, easy access, and wide applicability in organic synthesis, nickel has attracted intense attention. Over the past 50 years, nickel-catalyzed allylic substitution reactions have been extensively studied. The progresses on nickel-catalyzed allylic substitution reactions and their applications in organic synthesis are summarized according to bond formation and nucleophilic reagent.
引用
收藏
页码：15 / 27
页数：13
相关论文
共 118 条
  • [91] PALLADIUM(0)-CATALYZED ALLYLIC SUBSTITUTION WITH ALLYLIC ALKOXIDES AS SUBSTRATES
    STARY, I
    STARA, IG
    KOCOVSKY, P
    [J]. TETRAHEDRON, 1994, 50 (02) : 529 - 537
  • [92] ALLYLIC ALCOHOLS AS SUBSTRATES FOR THE PALLADIUM(0)-CATALYZED ALLYLIC SUBSTITUTION
    STARY, I
    STARA, IG
    KOCOVSKY, P
    [J]. TETRAHEDRON LETTERS, 1993, 34 (01) : 179 - 182
  • [93] Mechanistic Investigation of the Nickel-Catalyzed Suzuki Reaction of N,O-Acetals: Evidence for Boronic Acid Assisted Oxidative Addition and an Iminium Activation Pathway
    Sylvester, Kevin T.
    Wu, Kevin
    Doyle, Abigail G.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (41) : 16967 - 16970
  • [94] Palladium-catalyzed regiocontrolled and stereoselective alkylations of bis(trifluoroethyl) malonates with dienyl alcohols
    Takacs, JM
    Jiang, XT
    Leonov, AP
    [J]. TETRAHEDRON LETTERS, 2003, 44 (37) : 7075 - 7079
  • [95] Iridium-catalyzed formation of carbon-carbon and carbon-heteroatom bonds
    Takeuchi, Ryo
    Kezuka, Satoko
    [J]. SYNTHESIS-STUTTGART, 2006, (20): : 3349 - 3366
  • [96] Et3B-promoted, Pd(0)-catalyzed allylation of active methylene compounds with allylic alcohols
    Tamaru, Y
    Horino, Y
    Araki, M
    Tanaka, S
    Kimura, M
    [J]. TETRAHEDRON LETTERS, 2000, 41 (30) : 5705 - 5709
  • [97] Pincer-Nickel-Catalyzed Allyl-Aryl Coupling between Allyl Methyl Ethers and Arylzinc Chlorides
    Tao, Jian-Long
    Yang, Bo
    Wang, Zhong-Xia
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2015, 80 (24): : 12627 - 12634
  • [98] 4-hydroxylated piperidines and N-methyleuphococcinine (1-methyl-3-granatanone) from Picea (spruce) species.: Identification and synthesis
    Tawara, JN
    Lorenz, P
    Stermitz, FR
    [J]. JOURNAL OF NATURAL PRODUCTS, 1999, 62 (02): : 321 - 323
  • [99] Tenaglia A, 1999, ANGEW CHEM INT EDIT, V38, P2180, DOI 10.1002/(SICI)1521-3773(19990802)38:15<2180::AID-ANIE2180>3.3.CO
  • [100] 2-1
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