Recent Advances in Ni-Catalyzed Allylic Substitution Reactions

被引：34
|
作者：
Zhang, Huijun [1 ]
Gu, Qing [2 ]
You, Shuli [1 ,2 ]
机构：
[1] East China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 39卷 / 01期
基金：
中国国家自然科学基金;
关键词：
allylic substitution; asymmetric catalysis; nickel; transition metal; CROSS-COUPLING REACTION; ACTIVE METHYLENE-COMPOUNDS; DIRECT ALPHA-ALLYLATION; TRANSITION-METAL; BOND FORMATION; C-C; OXIDATIVE ADDITION; GRIGNARD-REAGENTS; NICKEL-COMPLEXES; SIMPLE ALKENES;
D O I：
10.6023/cjoc201809037
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Transition-metal catalyzed allylic substitution reaction is an important approach for constructing carbon-carbon bond and carbon-heteroatom bond. Due to its cheapness, easy access, and wide applicability in organic synthesis, nickel has attracted intense attention. Over the past 50 years, nickel-catalyzed allylic substitution reactions have been extensively studied. The progresses on nickel-catalyzed allylic substitution reactions and their applications in organic synthesis are summarized according to bond formation and nucleophilic reagent.
引用
收藏
页码：15 / 27
页数：13
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