A Simple and Effective Method for Catalytic Oxidation of Alcohols Using the Oxone/Bu4NHSO4 Oxidation System

被引：4
|
作者：
Yang, Y. X. [1 ,2 ,3 ]
An, X. Q. [1 ,2 ,3 ]
Kang, M. [1 ,2 ,3 ]
Zeng, W. [1 ,2 ,3 ]
Yang, Z. W. [1 ,2 ,3 ]
Ma, H. C. [1 ,2 ,3 ]
机构：
[1] Northwest Normal Univ, Minist Educ, Key Lab Ecofunct Polymer Mat, Lanzhou 730070, Peoples R China
[2] Northwest Normal Univ, Key Lab Ecoenvironm Polymer Mat Gansu Prov, Lanzhou 730070, Peoples R China
[3] Northwest Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Peoples R China
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 56卷 / 03期
关键词：
alcohols; oxidation; aldehydes; ketones; tetrabutylammonium hydrogen sulfate; ALDEHYDES; EFFICIENT; KETONES; OXONE;
D O I：
10.1134/S1070428020030240
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A simple and efficient procedure is reported for the oxidation of alcohols to carbonyl compounds with Oxone (potassium peroxymonosulfate) in the presence of tetrabutylammonium hydrogen sulfate as catalyst with excellent conversion and high selectivity using chloroform as solvent at room temperature. The efficiency of several phase-transfer catalysts in the oxidation of benzyl alcohols and benzydrol was studied. The proposed catalytic system was also evaluated in the oxidation of alcohols in water at room temperature.
引用
收藏
页码：521 / 523
页数：3
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