Electronic Structure of Polianylinine Modified by Copper and Zirconium Salts

被引：0
|
作者：
Shmatko, V. A. [1 ]
Myasoedova, T. N. [2 ]
Yalovega, G. E. [1 ]
机构：
[1] Southern Fed Univ, Rostov Na Donu 344090, Russia
[2] Southern Fed Univ, Inst Nanotechnol Elect & Equipment Engn, Taganrog 347928, Russia
来源：
OPTICS AND SPECTROSCOPY | 2020年 / 128卷 / 05期
关键词：
polyaniline; polyaniline-based composites; XANES; X-ray photoelectron spectroscopy; SPECTROSCOPIC CHARACTERIZATION; POLYANILINE; COMPOSITES; CHLORIDE;
D O I：
10.1134/S0030400X20050136
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
The features of the electronic structure and chemical bonds of PANI/Me composites (Me-Cu, Zr) have been studied spectroscopically. X-ray absorption spectroscopy, x-ray photoelectron spectroscopy, and infrared spectroscopy have been used for the research. It has been found that polyaniline is in a partially oxidized form in composites regardless of the type of modifying additive used, but it is more oxidized in PANI/Zr than in PANI/Cu. The chemical states of nitrogen in composites have been determined and the ratio of neutral and charged nitrogen groups is different.
引用
收藏
页码：610 / 615
页数：6
相关论文
共 50 条
  • [21] Electronic Structure of Copper Corroles
    Lemon, Christopher M.
    Huynh, Michael
    Maher, Andrew G.
    Anderson, Bryce L.
    Bloch, Eric D.
    Powers, David C.
    Nocera, Daniel G.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (06) : 2176 - 2180
  • [22] Structure and properties of NASICON synthesized by two different zirconium salts
    Heng-yao Dang
    Xing-min Guo
    Yong-ping Huang
    Jiang-qi Rong
    International Journal of Minerals, Metallurgy, and Materials, 2012, 19 : 768 - 773
  • [23] Structure and properties of NASICON synthesized by two different zirconium salts
    Dang, Heng-yao
    Guo, Xing-min
    Huang, Yong-ping
    Rong, Jiang-qi
    INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS, 2012, 19 (08) : 768 - 773
  • [24] Structure and properties of NASICON synthesized by two different zirconium salts
    Heng-yao Dang
    International Journal of Minerals Metallurgy and Materials, 2012, 19 (08) : 768 - 773
  • [25] The relation of copper and zinc salts to leaf structure
    Reed, HS
    AMERICAN JOURNAL OF BOTANY, 1939, 26 (01) : 29 - 33
  • [26] REPRODUCIBILITY OF THE SYNTHESIS OF MODIFIED ZIRCONIUM-PHOSPHATE (ZP) SAMPLES FROM ZIRCONIUM(IV) SALTS DIFFERING IN QUALITY
    BENDERSKAYA, LA
    BOICHINOVA, ES
    NIKOLAEVA, RB
    VINTER, IK
    JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1982, 55 (03): : 503 - 506
  • [27] The electronic structure of molten salts: A numerical approach
    Koslowski, T
    BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1996, 100 (02): : 95 - 100
  • [28] Ab Initio Electronic Structure Study of α-Zirconium and Hydrogen
    Iwasawa, Misako
    Ohnuma, Toshiharu
    Soneda, Naoki
    MATERIALS TRANSACTIONS, 2008, 49 (12) : 2765 - 2769
  • [29] Structure and electronic properties of zirconium and hafnium nitrides and oxynitrides
    Bazhanov, DI
    Knizhnik, AA
    Safonov, AA
    Bagatur'yants, AA
    Stoker, MW
    Korkin, AA
    JOURNAL OF APPLIED PHYSICS, 2005, 97 (04)
  • [30] Effect of Vacancies on the Electronic Structure and Bonding of Zirconium Nitride
    A. L. Ivanovskii
    N. I. Medvedeva
    S. V. Okatov
    Inorganic Materials, 2001, 37 : 459 - 465
12345