Crystal structure and magnetic properties of [{Co(H2O)2}2Mo(CN)8]•4 H2O, a three-dimensional cyanide-bridged bimetallic compound

被引：26

作者：

Tuna, F

Golhen, S

Ouahab, L

Sutter, JP ^{[1
]}

机构：

[1] Inst Chim Mat Condensee Bordeaux, CNRS, UPR 9048, F-33608 Pessac, France

[2] Univ Rennes 1, Lab Chim Solide & Inorgan Mol, UMR 6511, CNRS, F-35042 Rennes, France

[3] Romanian Acad, Inst Phys Chem, Bucharest 77208, Romania

来源：

COMPTES RENDUS CHIMIE | 2003年 / 6卷 / 03期

关键词：

cyanometalate; molybdenum complex; cobalt complex; magnetic properties; crystal structure; supramolecular material; porous framework;

D O I：

10.1016/S1631-0748(03)00053-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The three-dimensional cyano-bridged bimetallic compound of formula [{Co(H2O)(2)}(2)Mo(CN)(8)].4 H2O is described. The single-crystal X-ray structural determination revealed that the compound has a polymeric structure based on a network of [Mo-IV(CN)(8)] units and Co-II ions. Each Mo(CN)(8) building block is linked to Co ions through its eight CN ligands and each Co-II centre is connected to four Mo units forming a highly symmetrical three-dimensional framework with square-shaped channels running through the structure. The magnetic behaviour in the temperature range 2-300 K and spectroscopic data are reported as well.

引用

页码：377 / 383

页数：7

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