O2 structure Li2/3[Ni1/3Mn2/3]O2:: A new layered cathode material for rechargeable lithium batteries III.: Ion exchange

被引：58
|
作者：
Paulsen, JM [1 ]
Larcher, D [1 ]
Dahn, JR [1 ]
机构：
[1] Dalhousie Univ, Dept Phys, Halifax, NS B3H 3J5, Canada
来源：
JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2000年 / 147卷 / 08期
关键词：
D O I：
10.1149/1.1393617
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The ion exchange of Li for Na in P2-structure Na-2/3[Ni1/3Mn2/3]O-2 to make T2-structure Li-2/3[Ni1/3Mn2/3]O-2 is studied. Electron micrographs show that the hexagonal plate-like crystal habit is preserved during ion exchange. Ion exchange is successful and equivalent using both molten salts and concentrated Li+-containing aqueous solutions. By controlling the Li:Na ratio in the ion exchange, it is possible to prepare an intermediate phase of approximate composition Li1/3Na1/3[Ni1/3Mn2/3]O-2, where filled alkali layers of Li and Na alternate, thus doubling the c axis of the material. A summary of ion-exchange reactions of Li for Na in other layered Na-bronzes, such as P3-Na-2/3[Ni1/3Mn2/3]O-2, O3-Na[Ni1/2Mn1/2]O-2, P2-Na-2/3[CoxMn1-x]O-2, P3-Na-2/3[CoxMn1-x]O-2, P2-Na2/3CoO2, P2-Na-2/3[Fe1/3Mn2/3]O-2, P2-Na-2/3[Fe2/3Mn1/3]O-2, P2-Na-2/3[Mg1/3Mn2/3]O-2. P2-Na-2/3[Ni1/3Mn2/3]O-2, and O3-NaMnO2, is given. (C) 2000 The Electrochemical Society. S0013-4651(99)12-108-6. All rights reserved.
引用
收藏
页码：2862 / 2867
页数：6
相关论文
共 50 条
  • [41] Preparation and characterization of carbon-coated Li[Ni1/3Co1/3Mn1/3]O2 cathode material for lithium-ion batteries
    Lin, Bin
    Wen, Zhaoyin
    Wang, Xiuyan
    Liu, Yu
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2010, 14 (10) : 1807 - 1811
  • [42] Preparation and characterization of carbon-coated Li[Ni1/3Co1/3Mn1/3]O2 cathode material for lithium-ion batteries
    Bin Lin
    Zhaoyin Wen
    Xiuyan Wang
    Yu Liu
    Journal of Solid State Electrochemistry, 2010, 14 : 1807 - 1811
  • [43] Synthesis and electrochemical performances of core-shell structured Li[(Ni1/3Co1/3Mn1/3)0.8(Ni1/2Mn1/2)0.2]O2 cathode material for lithium ion batteries
    Lee, Ki-Soo
    Myung, Seung-Taek
    Sun, Yang-Kook
    JOURNAL OF POWER SOURCES, 2010, 195 (18) : 6043 - 6048
  • [44] Surface Structure, Morphology, and Stability of Li(Ni1/3Mn1/3Co1/3)O2 Cathode Material
    Garcia, Juan C.
    Bareno, Javier
    Yan, Jianhua
    Chen, Guoying
    Hauser, Andrew
    Croy, Jason R.
    Iddir, Hakim
    JOURNAL OF PHYSICAL CHEMISTRY C, 2017, 121 (15): : 8290 - 8299
  • [45] Recovery and heat treatment of the Li(Ni1/3Co1/3Mn1/3)O2 cathode scrap material for lithium ion battery
    Song, Dawei
    Wang, Xiaoqing
    Zhou, Enlou
    Hou, Peiyu
    Guo, Fenxia
    Zhang, Lianqi
    JOURNAL OF POWER SOURCES, 2013, 232 : 348 - 352
  • [46] Electrochemical properties of Li[Ni1/3Mn1/3Al1/3-xCox]O2 as a cathode material for lithium ion battery
    Ren, Haibo
    Lie, Xiang
    Peng, Zhenghe
    ELECTROCHIMICA ACTA, 2011, 56 (20) : 7088 - 7091
  • [47] AlF3-coated LiCoO2 and Li[Ni1/3Co1/3Mn1/3]O2 blend composite cathode for lithium ion batteries
    Lee, Ki-Soo
    Myung, Seung-Taek
    Kim, Dong-Won
    Sun, Yang-Kook
    JOURNAL OF POWER SOURCES, 2011, 196 (16) : 6974 - 6977
  • [48] Composition dependence of average and local structure of xLi(Li1/3Mn2/3)O2-(1-x)Li(Mn1/3Ni1/3Co1/3)O2 active cathode material for Li ion batteries
    Idemoto, Yasushi
    Inoue, Masahiro
    Kitamura, Naoto
    JOURNAL OF POWER SOURCES, 2014, 259 : 195 - 202
  • [49] Preparation of layered Li(Ni1/3Co1/3Mn1/3)O2 as positive material for lithium-ion secondary battery
    Hu Chuan-yue
    Wu Hong-tu
    Guo Jun
    Wang Xing-yan
    Yi Tao
    TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2007, 17 : S911 - S916
  • [50] Preparation of layered Li(Ni1/3Co1/3Mn1/3)O2 as positive material for lithium-ion secondary battery
    胡传跃
    吴宏图
    郭军
    汪形艳
    易涛
    Transactions of Nonferrous Metals Society of China, 2007, (S1) : 911 - 916
12345