Di-μ-acetato-κ3O,O′:O′;κ3O:O,O′-bis-[(acetato-κ2O,O′)bis(5-nitro-1,10-phenanthroline-κ2N,N′) cadmium]

被引：2
|
作者：
Cui, Fenghua [1 ,2 ]
Zhang, Shuxia [1 ]
机构：
[1] Henan Normal Univ, Dept Chem, Xinxiang 453007, Peoples R China
[2] Xinxiang Vocat & Tech Coll, Dept Engn & Technol, Xinxiang 453007, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
D O I：
10.1107/S1600536811032259
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the binuclear title compound, [Cd-2(C2H3O2)(4)(C12H7N3O2)(2)], the Cd-II cations are linked by carboxylate O atoms into a four-membered Cd2O2 rhombic ring with a Cd center dot center dot center dot Cd separation of 3.7515 (5) angstrom. Each Cd-II atom is seven-coordinated by a bidentate 5-nitro-1,10-phenanthroline (5-NO2-phen) ligand and two bidentate acetate anions, one of which also acts as a bridge linking the two Cd atoms. The crystal packing is stabilized by pi-pi interactions between the phen rings of neighboring molecules, with centroid-centroid distances of 3.491 (2) (intramolecular) and 3.598 (2) A (intermolecular).
引用
收藏
页码：M1247 / U842
页数：16
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