Synthesis of methyl 9-(benzo[d][1,3]dioxol-5-yl)-12-aryl(heteryl, cyclohexenyl)-11-oxo-7,8,9,10,11,12-hexahydrobenzo[b][4,7]phenanthroline-10-carboxylates

被引：1

作者：

Kozlov, N. G. ^{[1
]}

Tereshko, A. B. ^{[1
]}

机构：

[1] Natl Acad Sci Belarus, Inst Phys Organ Chem, Minsk 220072, BELARUS

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 47卷 / 08期

关键词：

Halogen Atom; Isomer Ratio; Isomer Mixture; Dichlorophenyl; Cyclohexenyl;

D O I：

10.1134/S1070428011080100

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By condensation of 6-aminoquinoline with methyl 2-(benzo[d][1,3]dioxol-5-yl)-4,6-dioxocyclohexanecarboxylate and aldehydes of aromatic, heteroaromatic, and cyclohexene series new 4,7-phenanthroline derivatives were synthesized. The reaction performed in 1-butanol proceeded regiospecifically and with a moderate degree of stereoselectivity resulting in a mixture of cis- and trans-methyl 9-(benzo-[d][1,3] dioxol-5-yl)-12-aryl(heteryl, cyclohexenyl)-11-oxo-7,8,9,10,11,12-hexahydrobenzo-[b][4,7]-phenanthroline-10-carboxylates (similar to 30: 70).

引用

页码：1181 / 1189

页数：9

共 50 条

[1] Synthesis of methyl 9-(benzo[d][1,3]dioxol-5-yl)-12-aryl(heteryl, cyclohexenyl)-11-oxo-7,8,9,10,11,12-hexahydrobenzo[b][4,7]phenanthroline-10-carboxylates
N. G. Kozlov
A. B. Tereshko
Russian Journal of Organic Chemistry, 2011, 47 : 1181 - 1189
[2] Synthesis of methyl 9-mesityl-12-aryl-11-oxo-7,8,9,10,11,12-hexahydrobenzo[a]- acridine-10-carboxylates
Kozlov, N. G.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2011, 47 (11) : 1710 - 1714
[3] Synthesis of methyl 9-mesityl-12-aryl-11-oxo-7,8,9,10,11,12-hexahydrobenzo[a]- acridine-10-carboxylates
N. G. Kozlov
Russian Journal of Organic Chemistry, 2011, 47 : 1710 - 1714
[4] Synthesis of Methyl 7-Aryl(hetaryl, cyclohexenyl)-10,10-dimethyl-8-oxo-7,8,9,10,11,12-hexahydrobenzo[b][1,7]phenanthroline-9-carboxylates
Kozlov, N. G.
Tereshko, A. B.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 46 (08) : 1223 - 1230
[5] Synthesis of methyl 7-aryl(hetaryl, cyclohexenyl)-10,10-dimethyl-8-oxo-7,8,9,10,11,12-hexahydrobenzo[b][1,7]phenanthroline-9-carboxylates
N. G. Kozlov
A. B. Tereshko
Russian Journal of Organic Chemistry, 2010, 46 : 1223 - 1230
[6] Synthesis of bis[2-methoxy-4-(11-oxo-7,8,9,10,11,12-hexahydrobenzo[a]acridin-12-yl)phenyl] succinates
Kozlov, N. G.
Dikusar, E. A.
Odnoburtsev, B. A.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 44 (10) : 1504 - 1507
[7] Synthesis of bis[2-methoxy-4-(11-oxo-7,8,9,10,11,12-hexahydrobenzo[a]acridin-12-yl)phenyl] succinates
N. G. Kozlov
E. A. Dikusar
B. A. Odnoburtsev
Russian Journal of Organic Chemistry, 2008, 44
[8] Synthesis of methyl 7-aryl(hetaryl, cyclohexenyl)-10-(1,3-benzodioxol-5-yl)-8-oxo-7,8,9,10,11,12-hexahydro-benzo[b][1,7]phenanthroline-9-carboxylates
Kozlov, N. G.
Tereshko, A. B.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 49 (09) : 1335 - 1343
[9] Synthesis of methyl 7-aryl(hetaryl, cyclohexenyl)-10-(1,3-benzodioxol-5-yl)-8-oxo-7,8,9,10,11,12-hexahydro-benzo[b][1,7]phenanthroline-9-carboxylates
N. G. Kozlov
A. B. Tereshko
Russian Journal of Organic Chemistry, 2013, 49 : 1335 - 1343
[10] Synthesis of methyl 12-aryl-9,9-dimethyl-11-oxo-7,8,9,10,11,12-hexahydrobenzo[a]acridine-10-carboxylate
Kozlov, N. G.
Bondarev, S. L.
Kadutskii, A. P.
Basalaeva, L. I.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 46 (02) : 202 - 208

← 1 2 3 4 5 →