Rapid Room-Temperature Synthesis of Zeolitic Imidazolate Frameworks by Using Mechanochemistry

被引:431
|
作者
Beldon, Patrick J. [1 ]
Fabian, Laszlo [2 ]
Stein, Robin S. [3 ]
Thirumurugan, A. [4 ]
Cheetham, Anthony K. [4 ]
Friscic, Tomislav [1 ]
机构
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
[2] Univ Coll Cork, Dept Chem, Cork, Ireland
[3] Bruker UK Ltd, Coventry CV4 9GH, W Midlands, England
[4] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England
关键词
grinding; imidazoles; mechanosynthesis; metal-organic frameworks; zeolite analogues; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; STEPWISE MECHANISM; EXTERNAL SURFACE; REACTIVITY; COCRYSTAL; NETWORKS; POLYMERS;
D O I
10.1002/anie.201005547
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Freshly ground: Improved mechanochemical methodologies, such as liquid-assisted grinding and ion- and liquid-assisted grinding enable the rapid and topologically selective synthesis of porous and nonporous zeolitic imidazolate frameworks with diverse topologies, at room temperature and directly from zinc oxide (see scheme). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:9640 / 9643
页数:4
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