REUSABLE POLYMER-SUPPORTED 2,2′-BIARYLPYRIDINE-COPPER COMPLEXES FOR HUISGEN [3+2] CYCLOADDITION IN WATER

被引：11

作者：

Suzuka, Toshimasa ^{[1
]}

Kawahara, Yamato ^{[1
]}

Ooshiro, Kazumasa ^{[1
]}

Nagamine, Takuya ^{[1
]}

Ogihara, Kazuhito ^{[1
]}

Higa, Matsutake ^{[1
]}

机构：

[1] Univ Ryukyus, Dept Chem Biol & Marine Sci, Okinawa 9030213, Japan

来源：

HETEROCYCLES | 2012年 / 85卷 / 03期

关键词：

Copper; Terpyridine; Click Chemistry; Triazole; Azide; CLICK CHEMISTRY; 1,4-DISUBSTITUTED 1,2,3-TRIAZOLES; 1,3-DIPOLAR CYCLOADDITION; CATALYZED CYCLOADDITION; EFFICIENT SYNTHESIS; ORGANIC AZIDES; LIGAND-FREE; ALKYNES; COPPER(I); ANALOGS;

D O I：

10.3987/COM-11-12405

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Polymer-supported 2,2'-biarylpyridine copper complexes were prepared and found to promote the Huisgen [3+2] cycloaddition reaction between azides and alkynes in water to give the corresponding triazoles in up to 95% isolated yield. The catalyst was recovered and reused several times without any loss in catalytic activity. ICP-AES analysis of the aqueous phase revealed barely detectable levels of copper residue.

引用

页码：615 / 626

页数：12

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