Analysis of the synthesis of 1,1-dibutoxyethane in a simulated moving-bed adsorptive reactor

被引：28

作者：

Graca, Nuno S. ^{[1
]}

Pais, Luis S. ^{[2
]}

Silva, Viviana M. T. M. ^{[1
]}

Rodrigues, Alirio E. ^{[1
]}

机构：

[1] Univ Porto, LSRE, Associate Lab LSRE LCM, Dept Chem Engn,Fac Engn, P-4200465 Oporto, Portugal

[2] Braganca Polytech Inst, Sch Technol & Management, P-5301857 Braganca, Portugal

来源：

CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION | 2011年 / 50卷 / 11-12期

关键词：

Simulated moving-bed reactors; Multifunctional reactors; Adsorption; Catalysis; Amberlyst; 15; ESTERIFICATION; CATALYSTS; BUTANOL;

D O I：

10.1016/j.cep.2011.08.004

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The synthesis of 1,1 -dibutoxyethane was carried out in a simulated moving-bed pilot unit LICOSEP 12-26 (Novasep, France) with 12 columns packed with the commercial ion-exchange resin Amberlyst 15 (Rohm & Haas, France). Experimentally the best raffinate purity obtained was 85% with a productivity of 5.04 kg L-1 d(-1) and a desorbent consumption of 13.5 L kg(-1). The TMBR model was used to construct reaction/separation regions and to study the influence of feed composition, switching time, flow rates and mass-transfer resistances on the SMBR performance. The SMBR process shows a potential to be a competitive, efficient and environmentally friendly way to produce 1,1-dibutoxyethane and other acetals. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：1214 / 1225

页数：12

共 50 条

[41] Simulated moving-bed technology in the sweetener industry
Rearick, DE
Kearney, M
Costesso, DD
CHEMTECH, 1997, 27 (09) : 36 - 40
[42] A SIMULATED COUNTERCURRENT MOVING-BED CHROMATOGRAPHIC REACTOR FOR THE OXIDATIVE COUPLING OF METHANE - EXPERIMENTAL RESULTS
TONKOVICH, ALY
CARR, RW
CHEMICAL ENGINEERING SCIENCE, 1994, 49 (24A) : 4647 - 4656
[43] Modeling of the simulated countercurrent moving-bed chromatographic reactor used for the oxidative coupling of methane
1600, Pergamon Press Inc, Tarrytown, NY, USA (49):
[44] MILD GASIFICATION OF COAL IN A MOVING-BED REACTOR
SUNDARAM, MS
FALLON, PT
STEINBERG, M
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1989, 197 : 7 - FUEL
[45] MODELING OF THE SIMULATED COUNTERCURRENT MOVING-BED CHROMATOGRAPHIC REACTOR USED FOR THE OXIDATIVE COUPLING OF METHANE
TONKOVICH, ALY
CARR, RW
CHEMICAL ENGINEERING SCIENCE, 1994, 49 (24A) : 4657 - 4665
[46] ANALYSIS OF THE COUNTER-CURRENT MOVING-BED CHROMATOGRAPHIC REACTOR.
Petroulas, T.
Aris, R.
Carr, R.W.
Computers & mathematics with applications, 1985, 11 (1-3): : 5 - 34
[47] Purification of monoclonal antibodies by simulated moving-bed chromatography
Gottschlich, N
Kasche, V
JOURNAL OF CHROMATOGRAPHY A, 1997, 765 (02) : 201 - 206
[48] A SIMPLIFIED DESIGN METHOD FOR A SIMULATED MOVING-BED ADSORBER
HASHIMOTO, K
SHIRAI, Y
MORISHITA, M
ADACHI, S
KAGAKU KOGAKU RONBUNSHU, 1990, 16 (01) : 193 - 196
[49] A new concept for operating simulated moving-bed processes
Kloppenburg, E
Gilles, ED
CHEMICAL ENGINEERING & TECHNOLOGY, 1999, 22 (10) : 813 - +
[50] Dynamics of simulated moving-bed adsorption separation processes
Lu, ZP
Ching, CB
SEPARATION SCIENCE AND TECHNOLOGY, 1997, 32 (12) : 1993 - 2010

← 1 2 3 4 5 →