Structures of sesquiterpene polyol alkaloids from Tripterygium hypoglaucum

被引:33
|
作者
Duan, HQ [1 ]
Takaishi, Y [1 ]
机构
[1] Univ Tokushima, Fac Pharmaceut Sci, Tokushima 7708505, Japan
关键词
Tripterygium hypoglaucum; Celastraceae; root bark; sesquiterpene; pyridine alkaloid; hypoglaunine;
D O I
10.1016/S0031-9422(98)00439-7
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Esters of four new (hypoglaunine A, B, C and D) and five known sesquiterpene polyalcohol esters have been isolated from the root barks of Tripterygium hypoglaucum. The structures of the new compounds were elucidated at 1,2,5,7,8-pentaacetoxy-11-furanoly-4-hydroxy-3,15[2'-hydroxy-2',3'-dimethyl-3'(3 "-carboxy-4 "-pyridyl)-probanoic acid]dicarbolactone-dihydroagarofuran, 1,5,7,8,11-pentaacetoxy-2-furanoyl-4-hydroxy-3,15[2'-hydroxy-2',3'-dimethyl-3'(3 "-carboxy-4 "-pyridyl)-propanoic acid]dicarbolactone-dihydroagarofuran, 1,5,7,8,11-pentaacetoxy-2-benzoyl-4-hydroxy-3,15[2'-hydroxy-2',3'-dimethyl-3'(3 "-carboxy-4 "-pyridyl)-propanoic acid]dicarbolactone-dihydroagarofuran and 1,2,5,7,8-pentaacetoxy-11-furanoyl-4-hydroxy-3,15[2',3'-dimethyl-3'(3 "-carboxy-4 "-pyridyl)-propanoic acid]dicarbolactone-dihydroagarofuran by spectroscopic means. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2185 / 2189
页数:5
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