Shaping Covalent Triazine Frameworks for the Hydrogenation of Carbon Dioxide to Formic Acid

被引：73
|
作者：
Bavykina, Anastasiya V. [1 ]
Rozhko, Elena [1 ]
Goesten, Maarten G. [1 ,2 ]
Wezendonk, Tim [1 ]
Seoane, Beatriz [1 ]
Kapteijn, Freek [1 ]
Makkee, Michiel [1 ]
Gascon, Jorge [1 ]
机构：
[1] Delft Univ Technol, Catalysis Engn ChemE, Julianalaan 136, NL-2628 BL Delft, Netherlands
[2] Eindhoven Univ Technol, Dept Chem Engn & Chem Mol Catalysis, Kranenveld 14, NL-5600 MB Eindhoven, Netherlands
来源：
CHEMCATCHEM | 2016年 / 8卷 / 13期
关键词：
carbon dioxide hydrogenation; catalyst shaping; covalent triazine frameworks; formic acid; CATALYTIC-HYDROGENATION; CO2; OXIDATION;
D O I：
10.1002/cctc.201600419
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A facile one-step method to shape covalent triazine frameworks (CTFs) for catalytic applications is reported. Phase inversion of the CTF powder by using a polyimide as a binder in a microfluidic device results in the formation of composite spheres with accessible CTF porosity and a high mechanical and thermal stability. The fabricated spheres can be used to host organometallic complexes. The obtained shaped catalysts, Ir@CTF spheres, are active and fully recyclable in the direct hydrogenation of carbon dioxide into formic acid under mild reaction conditions (20 bar and 50-90 degrees C) and in the dehydrogenation of formic acid.
引用
收藏
页码：2217 / 2221
页数：5
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