β-isocupreidine-hexafluoroisopropyl acrylate method for asymmetric Baylis-Hillman reactions

被引：77

作者：

Nakano, A ^{[1
]}

Kawahara, S ^{[1
]}

Akamatsu, S ^{[1
]}

Morokuma, K ^{[1
]}

Nakatani, M ^{[1
]}

Iwabuchi, Y ^{[1
]}

Takahashi, K ^{[1
]}

Ishihara, J ^{[1
]}

Hatakeyama, S ^{[1
]}

机构：

[1] Nagasaki Univ, Grad Sch Biomed Sci, Nagasaki 8528521, Japan

来源：

TETRAHEDRON | 2006年 / 62卷 / 2-3期

关键词：

beta-isocupreidine; 1,1,1,3,3,3-hexafluoroisopropyl acrylate; organic catalysis;

D O I：

10.1016/j.tet.2005.09.072

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Key features of the beta-isocupreidine (beta-ICD)-catalyzed asymmetric Baylis-Hillman reaction of aldehydes with 1,1,1,3,3,3-hexafluoroisopropyl acrylate (HFIPA) are presented. In addition, an improved method using azeotropically dried beta-ICD is described. (c) 0 2005 Elsevier Ltd. All rights reserved.

引用

页码：381 / 389

页数：9

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