Facile light-initiated radical generation from 4-substituted pyridine under ambient conditions

被引：7

作者：

Nakayama, Ami ^{[1
]}

Kimata, Haru ^{[1
]}

Marumoto, Kazuhiro ^{[1
,2
]}

Yamamoto, Yohei ^{[1
,2
]}

Yamagishi, Hiroshi ^{[1
,2
]}

机构：

[1] Univ Tsukuba, Fac Pure & Appl Sci, Dept Mat Sci, 1-1-1 Tennodai, Tsukuba, Ibaraki 3058573, Japan

[2] Univ Tsukuba, Tsukuba Res Ctr Energy Mat Sci TREMS, 1-1-1 Tennodai, Tsukuba, Ibaraki 3058573, Japan

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 51期

关键词：

PHOTOLYSIS; MECHANISM;

D O I：

10.1039/d0cc02538k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photochemical reactions that generate stable radical species under ambient conditions find unique applications in materials science. Here we present a facile photogeneration of a stable radical species from a 4-substituted pyridine derivative in the presence of water and air at room temperature. The radical generation reaction accompanies a visible colour change to green and is repeatable multiple times.

引用

页码：6937 / 6940

页数：4

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