Reverse micelle facilitated synthesis of nanostructured polyaniline as the counter electrode materials in dye-sensitized solar cells

被引：13

作者：

Utami, Annisa Nurul ^{[1
]}

Reza, Muhammad ^{[1
]}

Benu, Didi Prasetyo ^{[1
,2
]}

Fatya, Alvian Ikhsanul ^{[1
]}

Yulianto, Brian ^{[3
,4
]}

Suendo, Veinardi ^{[1
,4
]}

机构：

[1] Inst Teknol Bandung, Fac Math & Nat Sci, Div Inorgan & Phys Chem, Bandung, Indonesia

[2] Univ Timor, Dept Chem, Kefamenanu, Indonesia

[3] Inst Teknol Bandung, Dept Engn Phys, Bandung, Indonesia

[4] Inst Teknol Bandung, Res Ctr Nanosci & Nanotechnol, Bandung, Indonesia

来源：

POLYMER-PLASTICS TECHNOLOGY AND MATERIALS | 2020年 / 59卷 / 12期

关键词：

Counter-electrode materials; dye-sensitized solar cell; emulsion polymerization; nanostructured polyaniline; polyglyceryl-2-dipolyhydroxystearate; reverse micelle; EMULSION POLYMERIZATION; CONDUCTING POLYMERS; FABRICATION; EMERALDINE; NANOFIBERS; SALT;

D O I：

10.1080/25740881.2020.1738477

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We report a reverse-micelle emulsion polymerization of nanostructured PANI using a nonionic surfactant Polyglyceryl-2-Dipolyhydroxystearate (PGPH) at various concentrations from 2% to 6% (v/v). SEM images show that the obtained morphologies are irregular agglomerates at low PGPH concentration and relatively regular granules at high PGPH concentration. FTIR and Raman spectra show that the synthesized PANI is in the form of Emeraldine salt (PANI ES) with electrical conductivity around 10(-3) S cm(-1). Photovoltaic current-voltage (J-V) measurements show the highest power conversion efficiency is achieved at 1.71% at 6% (v/v) of PGPH.

引用

页码：1350 / 1358

页数：9

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