Supported Catalysis in Continuous-Flow Microreactors

被引：288

作者：

Munirathinam, Rajesh ^{[1
]}

Huskens, Jurriaan ^{[1
]}

Verboom, Willem ^{[1
]}

机构：

[1] Univ Twente, MESA Inst Nanotechnol, Lab Mol Nanofabricat, NL-7500 AE Enschede, Netherlands

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2015年 / 357卷 / 06期

关键词：

enzyme catalysis; microreactors; nanoparticles; organocatalysis; packed-bed microreactors; supported catalysts; wall-coated microreactors; MICRO REACTION TECHNOLOGY; PACKED-BED MICROREACTORS; ORGANIC-SYNTHESIS; MICROSTRUCTURED REACTORS; CHEMICAL-SYNTHESIS; BENZYL ALCOHOL; CAPILLARY MICROREACTORS; HETEROGENEOUS CATALYSIS; HYDROGENATION REACTIONS; MICROFLUIDIC REACTOR;

D O I：

10.1002/adsc.201401081

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This review surveys the recent developments to perform heterogeneous catalysis in continuous-flow microreactors. Three different types, namely, (i) packed-bed, (ii) monolithic, and (iii) wall-coated approaches are discussed to implement various kinds of catalysts in a microreactor. In addition, the applications of these supported catalysts to perform a variety of organic reactions are described. Furthermore, advantages of catalytic microreactors over classical batch reactors on one or more aspects of the reaction, such as rate, conversion, selectivity, and enantioselectivity are presented.

引用

页码：1093 / 1123

页数：31

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