Supported Catalysis in Continuous-Flow Microreactors

被引:288
|
作者
Munirathinam, Rajesh [1 ]
Huskens, Jurriaan [1 ]
Verboom, Willem [1 ]
机构
[1] Univ Twente, MESA Inst Nanotechnol, Lab Mol Nanofabricat, NL-7500 AE Enschede, Netherlands
关键词
enzyme catalysis; microreactors; nanoparticles; organocatalysis; packed-bed microreactors; supported catalysts; wall-coated microreactors; MICRO REACTION TECHNOLOGY; PACKED-BED MICROREACTORS; ORGANIC-SYNTHESIS; MICROSTRUCTURED REACTORS; CHEMICAL-SYNTHESIS; BENZYL ALCOHOL; CAPILLARY MICROREACTORS; HETEROGENEOUS CATALYSIS; HYDROGENATION REACTIONS; MICROFLUIDIC REACTOR;
D O I
10.1002/adsc.201401081
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
This review surveys the recent developments to perform heterogeneous catalysis in continuous-flow microreactors. Three different types, namely, (i) packed-bed, (ii) monolithic, and (iii) wall-coated approaches are discussed to implement various kinds of catalysts in a microreactor. In addition, the applications of these supported catalysts to perform a variety of organic reactions are described. Furthermore, advantages of catalytic microreactors over classical batch reactors on one or more aspects of the reaction, such as rate, conversion, selectivity, and enantioselectivity are presented.
引用
收藏
页码:1093 / 1123
页数:31
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