Protic onium salts-catalyzed synthesis of 5-aryl-2-oxazolidinones from aziridines and CO2 under mild conditions

被引：86
|
作者：
Yang, Zhen-Zhen [1 ]
Li, Yu-Nong
Wei, Yang-Yang
He, Liang-Nian
机构：
[1] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China
来源：
GREEN CHEMISTRY | 2011年 / 13卷 / 09期
基金：
中国国家自然科学基金;
关键词：
CARBON-DIOXIDE; SELECTIVE SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; CHEMICAL FIXATION; HIGHLY EFFICIENT; CYCLOADDITION; LIQUID; AMINES; OXAZOLIDINONES; CONVERSION;
D O I：
10.1039/c1gc15581d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Protic onium salts, e. g. pyridium iodide, proved to be highly efficient and recyclable catalysts for the selective synthesis of 5-aryl-2-oxazolidinones under a CO2 atmosphere at room temperature, presumably due to aziridine activation assisted by hydrogen bonding on the basis of H-1 NMR and in situ FT IR under CO2 pressure study.
引用
收藏
页码：2351 / 2353
页数：3
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