Protic onium salts-catalyzed synthesis of 5-aryl-2-oxazolidinones from aziridines and CO2 under mild conditions

被引：86

作者：

Yang, Zhen-Zhen ^{[1
]}

Li, Yu-Nong

Wei, Yang-Yang

He, Liang-Nian

机构：

[1] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China

来源：

GREEN CHEMISTRY | 2011年 / 13卷 / 09期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE; SELECTIVE SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; CHEMICAL FIXATION; HIGHLY EFFICIENT; CYCLOADDITION; LIQUID; AMINES; OXAZOLIDINONES; CONVERSION;

D O I：

10.1039/c1gc15581d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Protic onium salts, e. g. pyridium iodide, proved to be highly efficient and recyclable catalysts for the selective synthesis of 5-aryl-2-oxazolidinones under a CO2 atmosphere at room temperature, presumably due to aziridine activation assisted by hydrogen bonding on the basis of H-1 NMR and in situ FT IR under CO2 pressure study.

引用

页码：2351 / 2353

页数：3

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