Effect of pressure on the Raman anomaly of zinc-blende CuBr and Raman spectra of high-pressure phases -: art. no. 064301

被引:16
|
作者
Manjón, FJ [1 ]
Serrano, J [1 ]
Loa, I [1 ]
Syassen, K [1 ]
Lin, CT [1 ]
Cardona, M [1 ]
机构
[1] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany
关键词
D O I
10.1103/PhysRevB.64.064301
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Raman spectra of isotopically pure CuBr (Cu-63 Br-81) were measured under hydrostatic pressures up to 10 GPa at 10 K. The anomalous line shape of the longitudinal-optic (LO) scattering in the zinc-blende phase (CuBr-III, 0-4 GPa), consisting of a broad structure between 155 and 177 cm(-1), exhibits a continuous change with pressure and develops into a narrow LO phonon peak near 4 GPa. The disappearance of the LO Raman anomaly as well as the pronounced broadening of the TO mode with pressure are explained in terms of pressure-dependent third-order anharmonic interactions with two-phonon states. A Fermi resonance model, which is based on a shell model fit of available phonon dispersion data, fully accounts for the changes in Raman line shapes under pressure. Low-temperature Raman spectra of the tetragonal CuBr-IV and cubic CuBr-V high-pressure phases are also reported. An assignment of the observed Raman modes of these phases is proposed.
引用
收藏
页码:643011 / 643019
页数:9
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