Polar substituent and solvent effects on the kinetics of radical reactions with thiols

被引：56

作者：

Tronche, C

Martinez, FN

Horner, JH

Newcomb, M

Senn, M

Giese, B

机构：

[1] WAYNE STATE UNIV,DEPT CHEM,DETROIT,MI 48202

[2] UNIV BASEL,DEPT CHEM,CH-4056 BASEL,SWITZERLAND

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 33期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0040-4039(96)01241-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rates of thiol trapping of radicals depend upon polar substituents (Table 1) and solvent effects (Table 2). The rate accelerating effect of water on the reactions of biologically relevant radicals is of special importance. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：5845 / 5848

页数：4

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