Synthesis, Crystal Structure and Luminescent Property of a Ternary Complex [Cd(sfdb)(3-pytpy)]2•2H2O (H2sfdb=4,4′-Sulfonyldibenzoic Acid, 3-pytpy=4′-(3-Pyridyl)-2,2′:6′,2"-Terpyridine)

被引：8

作者：

Gou, Lei ^{[1
]}

Chen, Xiao-Li ^{[2
]}

机构：

[1] Changan Univ, Sch Mat Sci & Engn, Xian 710061, Shaanxi, Peoples R China

[2] Coll Chem & Chem Engn, Shaanxi Key Lab Chem React Engn, Yanan 716000, Shaanxi, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2010年 / 40卷 / 10期

关键词：

Synthesis; Crystal structure; Luminescent property; COORDINATION POLYMERS; TERPYRIDINE;

D O I：

10.1007/s10870-010-9754-2

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A new ternary complex [Cd(sfdb)(3-pytpy)](2)center dot 2H(2)O (H(2)sfdb = 4,4'-Sulfonyldibenzoic acid, 3-pytpy = 4'-(3-pyridyl)-2,2': 6',2 ''-terpyridine) 1 has been hydrothermally synthesized and characterized by the elemental analysis, IR spectroscopy and single crystal X-ray diffraction. X-ray diffraction analysis reveals that 1 (C34H24CdN4O7S) crystallizes in triclinic space group P-1, features an interesting 1D channel-containing supramolecular structure constructed from grid-like dimers via pi-pi stacking interactions. Unit cell parameters for 1: a = 8.866(2) angstrom, b = 11.083(3) angstrom, c = 15.790(4) angstrom, alpha = 103.612(4)degrees, beta = 95.044(3)degrees, gamma = 101.083(4)degrees and Z = 2. The luminescent spectrum shows the emission peak of complex 1 is at 392 nm which is attributed to the intraligand transition.

引用

页码：859 / 862

页数：4

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