Tandem Catalysis: Alcohol Oxidation and C-C Bond Formation via C-H Bond Activation

被引：20
|
作者：
Simon, Marc-Olivier [1 ]
Ung, Gael [1 ]
Darses, Sylvain [1 ]
机构：
[1] Ecole Natl Super Chim Paris, CNRS, Lab Charles Friedel, UMR 7223, F-75231 Paris 05, France
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2011年 / 353卷 / 07期
关键词：
alcohols; arylation; C-H activation; oxidation; ruthenium; DIRECT ARYLATION; HYDROGEN-TRANSFER; INTERMOLECULAR HYDROARYLATION; HETEROAROMATIC-COMPOUNDS; BORROWING HYDROGEN; RUTHENIUM CATALYST; ATOM ECONOMY; FUNCTIONALIZATION; ALKENES; ARENES;
D O I：
10.1002/adsc.201000884
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A tandem process involving oxidation of a benzylic alcohol functionality followed by hydroarylation is described. These two atom-economic sequences are very convenient to access functionalized aromatic ketones, using simple ruthenium trichloride as catalyst precursor. Moreover they appear to be highly compatible, tolerant, and selective toward various functional groups, and the ease of the protocol should make it very convenient for synthetic purposes.
引用
收藏
页码：1045 / 1048
页数：4
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