Organocatalytic asymmetric oxidation

被引:0
|
作者
Gong, Bin [1 ]
Meng, Qing-Wei [1 ]
Gao, Zhan-Xian [1 ]
机构
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116023, Peoples R China
关键词
organocatalyst; asymmetric oxidation; asymmetric epoxidation; alpha-hydroxylation;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A great application potential of organocatalysts has been displayed in asymmetric oxidation. Asymmetric epoxidation of alpha,beta-unsaturated aldehyde/ketone as well as olefin, and asymmetric alpha-hydroxylation of carbonyl compounds catalyzed by various types of organocatalysts are reviewed in this paper. The characteristics and mechanism of organocatalysis are also depicted in detail.
引用
收藏
页码:588 / 597
页数:10
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