An efficient and sustainable synthesis of NHC gold complexes

被引：41

作者：

Johnson, Alice ^{[1
]}

Concepcion Gimeno, M. ^{[1
]}

机构：

[1] Univ Zaragoza, CSIC, ISQCH, Dept Quim Inorgan, E-50009 Zaragoza, Spain

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 62期

关键词：

N-HETEROCYCLIC CARBENE; STRUCTURAL-CHARACTERIZATION; BOND FORMATION; C-N; METAL-COMPLEXES; CATALYSIS; PALLADIUM; COORDINATION; PRECATALYST; PLATINUM;

D O I：

10.1039/c6cc05190a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple, efficient and sustainable method for the general synthesis of NHC gold(I) complexes is described. The reaction of imidazolium salts, of different electronic and steric requirements, with (AuX(tht)] (tht = tetrahydrothiophene) derivatives, in the presence of NBu4(acac), in air and at room temperature leads to the NHC gold species in good yields and with very short reaction times.

引用

页码：9664 / 9667

页数：4

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