An efficient and sustainable synthesis of NHC gold complexes

被引：41
|
作者：
Johnson, Alice [1 ]
Concepcion Gimeno, M. [1 ]
机构：
[1] Univ Zaragoza, CSIC, ISQCH, Dept Quim Inorgan, E-50009 Zaragoza, Spain
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 62期
关键词：
N-HETEROCYCLIC CARBENE; STRUCTURAL-CHARACTERIZATION; BOND FORMATION; C-N; METAL-COMPLEXES; CATALYSIS; PALLADIUM; COORDINATION; PRECATALYST; PLATINUM;
D O I：
10.1039/c6cc05190a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A simple, efficient and sustainable method for the general synthesis of NHC gold(I) complexes is described. The reaction of imidazolium salts, of different electronic and steric requirements, with (AuX(tht)] (tht = tetrahydrothiophene) derivatives, in the presence of NBu4(acac), in air and at room temperature leads to the NHC gold species in good yields and with very short reaction times.
引用
收藏
页码：9664 / 9667
页数：4
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