Photoswitching tetranuclear rhenium(I) tricarbonyl diimine complexes with a stilbene-like bridging ligand

被引:39
|
作者
Lin, Ju-Ling [1 ]
Chen, Chih-Wei [1 ]
Sun, Shih-Sheng [1 ]
Lees, Alistair J. [2 ]
机构
[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan
[2] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA
关键词
ENERGY-TRANSFER; PHOTOPHYSICAL PROPERTIES; SUPRAMOLECULAR SYSTEMS; CIS ISOMERIZATION; PHOTOCHEMISTRY; LUMINESCENCE; PHOTOISOMERIZATION; MECHANISMS;
D O I
10.1039/c1cc11272d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Highly efficient photoswitching tetranuclear rhenium(I) tricarbonyl diimine complexes with a stilbene-like bridging ligand are reported. The ability to directly populate excited states localized on the bridging ligand is the key for the observed efficient photoisomerization.
引用
收藏
页码:6030 / 6032
页数:3
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