A Suzuki Approach to Quinone-Based Diarylethene Photochromes

被引:7
|
作者
Patel, Dinesh G. [1 ]
Mitchell, Travis B. [2 ]
Myers, Shea D. [1 ]
Carter, Dorothy A. [1 ]
Novak, Frank A. [1 ]
机构
[1] Penn State Univ, Dept Chem, Hazleton, PA 18202 USA
[2] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA
来源
JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 85卷 / 04期
基金
美国国家科学基金会;
关键词
TETRAARYL-P-BENZOQUINONES; ARYLBORONIC ACIDS; PHOTOSWITCHABLE DIARYLETHENES; TRANSPORT CHARACTERISTICS; DESIGN; LIGHT; BORYLATION; HETEROARENES; DERIVATIVES; MODULATION;
D O I
10.1021/acs.joc.9b02632
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Diarylethene photochromes show promise for use in advanced organic electronic and photonic materials with burgeoning considerations for biological applications; however, these compounds typically require UV light for photoswitching in at least one direction, thus limiting their appeal. We here introduce a naphthoquinone-based diarylethene that switches between open and closed forms with visible light. The synthesis of this quinone diarylethene relies on Suzuki methodology, allowing for the inclusion of functional groups not otherwise accessible with current synthetic routes.
引用
收藏
页码:2646 / 2653
页数:8
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