A trimetallic compound containing Zn-Zr bonds:: Cp2Zr(ZnR)2 (Cp = C5H5; r = C6H3-2,6-(2,4,6-i-Pr3C6H2)2)

被引：25
|
作者：
Wang, Yuzhong
Quillian, Brandon
Wannere, Chaitanya S.
Wei, Pingrong
Schleyer, Paul v. [1 ]
Robinson, Gregory H.
机构：
[1] Univ Georgia, Dept Chem, Athens, GA 30602 USA
[2] Univ Georgia, Ctr Computat Chem, Athens, GA 30602 USA
来源：
ORGANOMETALLICS | 2007年 / 26卷 / 12期
关键词：
D O I：
10.1021/om700319k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
m-Terphenylzinc iodides RZnI2Li(OEt2)(2) (1) and RZnI (2) (R = C6H3-2,6-(2,4,6-i-Pr3C6H2)(2)) were prepared and structurally characterized. The sodium metal reduction of Cp2ZrCl2 with 2 afforded Cp2Zr(ZnR)(2) (3) as the first structurally characterized compound containing a Zn-Zr bond. The nature of the unique Zn-Zr bond for 3 was further probed by DFT computations.
引用
收藏
页码：3054 / 3056
页数：3
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