A trimetallic compound containing Zn-Zr bonds:: Cp2Zr(ZnR)2 (Cp = C5H5; r = C6H3-2,6-(2,4,6-i-Pr3C6H2)2)

被引：25

作者：

Wang, Yuzhong

Quillian, Brandon

Wannere, Chaitanya S.

Wei, Pingrong

Schleyer, Paul v. ^{[1
]}

Robinson, Gregory H.

机构：

[1] Univ Georgia, Dept Chem, Athens, GA 30602 USA

[2] Univ Georgia, Ctr Computat Chem, Athens, GA 30602 USA

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 12期

关键词：

D O I：

10.1021/om700319k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

m-Terphenylzinc iodides RZnI2Li(OEt2)(2) (1) and RZnI (2) (R = C6H3-2,6-(2,4,6-i-Pr3C6H2)(2)) were prepared and structurally characterized. The sodium metal reduction of Cp2ZrCl2 with 2 afforded Cp2Zr(ZnR)(2) (3) as the first structurally characterized compound containing a Zn-Zr bond. The nature of the unique Zn-Zr bond for 3 was further probed by DFT computations.

引用

页码：3054 / 3056

页数：3

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