Modelling of wax deposition by perturbed hard sphere chain equation of state

被引:5
|
作者
Bazooyar, Bahamin [3 ]
Shaahmadi, Fariborz [2 ]
Jomekian, Abolfazl [3 ]
Darabkhani, Hamidreza Gohari [1 ]
机构
[1] Staffordshire Univ, Sch Engn & Creat Art, Stoke On Trent ST4 2DE, Staffs, England
[2] Petr Univ Technol, Ahvaz Fac Petr Engn, POB 6198144471, Ahvaz, Iran
[3] Esfarayen Univ Technol, Dept Chem & Mat Engn, Esfarayen, Iran
关键词
Solid-liquid equilibria; Paraffin; WAT; n-alkane; Hydrocarbon; ASPHALT FLOCCULATION; PRECIPITATION; EQUILIBRIA; FLUIDS;
D O I
10.1016/j.petrol.2019.106657
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
This article presents a model to predict the wax appearance temperature (WAT) and the quantity of wax deposition in eight different n-alkane mixtures using a correlative technique. The perturbed hard sphere chain equation of state (PHSC EoS) was employed in conjunction with the multi-solid model to describe the liquid-liquid and solid-liquid equilibria. The results are compared with experimental data. The results showed that PHSC EoS for some mixture of n-alkanes can perceptibly outperform the sole solid solution theory, improving the modelling of wax deposition quantities and wax appearance temperature by giving predictions closer to experimental values.
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页数:7
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