Hetero Diels-Alder reaction between 2,3-dimethyl-1,3-butadiene and perfluorooctanonitrile under high pressure

被引：13

作者：

Junge, H ^{[1
]}

Oehme, G ^{[1
]}

机构：

[1] Univ Rostock, Inst Organ Katalyseforsch, D-18055 Rostock, Germany

来源：

TETRAHEDRON | 1998年 / 54卷 / 37期

关键词：

Diels-Alder reactions; dienes; nitriles; pyridines;

D O I：

10.1016/S0040-4020(98)00659-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

3,4-Dimethyl-6-perfluoroheptyl-2,5-dihydridine (1) is obtained by hetero Diels-Alder reaction between 2,3dimethyl-1,3-butadiene and perfluorooctanonitrile at 50 degrees C and pressures of 1 and 1500 bar, respectively. 1 gradually eliminates hydrogen to give 3,4-dimethyl-6-perfluoroheptylpyridine (2). The investigation of influence of high pressure on this reaction showed a significant increase of yields of both heterocyclic compounds at 1500 bar. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：11027 / 11032

页数：6

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