Tetrathiafulvalene-based radical cation salts with transition metal bis(dicarbollide) anions

被引：23

作者：

Bregadze, Vladimir I. ^{[1
]}

Dyachenko, Oleg A. ^{[2
]}

Kazheva, Olga N. ^{[2
]}

Kravchenko, Andrey V. ^{[3
]}

Sivaev, Igor B. ^{[1
]}

Starodub, Vladimir A. ^{[4
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia

[3] Kharkov Natl Univ, Dept Chem, UA-61077 Kharkov, Ukraine

[4] Uniwersytet Jana Kochanowskiego, Inst Chem, PL-25406 Kielce, Poland

来源：

CRYSTENGCOMM | 2015年 / 17卷 / 26期

基金：

俄罗斯基础研究基金会;

关键词：

STRUCTURAL-CHARACTERIZATION; ELECTRICAL-CONDUCTIVITY; MOLECULAR CONDUCTORS; FULVALENIUM SALTS; MAGNETIC-PROPERTIES; ORGANIC CONDUCTORS; BEDT-TTF; COBALT; DERIVATIVES; BORON;

D O I：

10.1039/c5ce00835b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Radical cation salts based on derivatives of tetrathiafulvalene and sandwiched transition metal bis(dicarbollide) anions are of great interest in the development of new molecular conducting materials. The data on their synthesis, crystal structure, and electrical and magnetic properties were reviewed. The effect of various substituents in the metallacarborane anion on the structure and physical properties of their tetrathiafulvalene-based radical cation salts was analyzed. Relationships between the crystal structure and properties of the tetrathiafulvalene-based radical cation salts containing sandwiched transition metal bis(1,2-dicarbollide) anions are discussed.

引用

页码：4754 / 4767

页数：14

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