Selective oxidations of sulfides to sulfoxides using immobilised cerium alkyl phosphonate

被引:25
|
作者
Al-Hashimi, M [1 ]
Roy, G [1 ]
Sullivan, AC [1 ]
Wilson, JRH [1 ]
机构
[1] Queen Mary Univ London, Dept Chem, London E1 4NS, England
关键词
sulfide; sulfoxide; oxidation; cerium; phosphonate; silica; immobilised reagents;
D O I
10.1016/j.tetlet.2005.04.079
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A range of sulfides can be selectively oxidised to the corresponding sulfoxides in good yields using catalytic quantities of immobilised cerium alkyl phosphonate and either sodium brornate or tert-butyl hydroperoxide as oxidants. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4365 / 4368
页数:4
相关论文
共 50 条
  • [31] Highly selective 30% hydrogen peroxide oxidation of sulfides to sulfoxides using micromixing
    Noguchi, Takuya
    Hirai, Yoshiro
    Kirihara, Masayuki
    CHEMICAL COMMUNICATIONS, 2008, (26) : 3040 - 3042
  • [32] Selective trifluorination of alkyl aryl sulfides using IF5
    Ayuba, S
    Hiramatsu, C
    Fukuhara, T
    Hara, S
    TETRAHEDRON, 2004, 60 (50) : 11445 - 11451
  • [33] An efficient and selective photocatalytic system for the oxidation of sulfides to sulfoxides
    Zen, JM
    Liou, SL
    Kumar, AS
    Hsia, MS
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (05) : 577 - +
  • [34] A selective and convenient oxidation of sulfides to sulfoxides with trichloroisocyanuric acid
    Xiong, ZX
    Huang, NP
    Zhong, P
    SYNTHETIC COMMUNICATIONS, 2001, 31 (02) : 245 - 248
  • [35] A selective conversion of sulfides to sulfoxides in 3-fluorophenol
    Xu, WL
    Li, YZ
    Zhang, QS
    Zhu, HS
    SYNTHETIC COMMUNICATIONS, 2004, 34 (02) : 231 - 237
  • [37] SELECTIVE MOLECULAR-OXYGEN OXIDATION OF ALKYL SULFIDES TO SULFOXIDES CATALYZED BY DIHALOTETRAKIS (DIMETHYLSULFOXIDE) RUTHENIUM(II) COMPLEXES
    RILEY, DP
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1983, 186 (AUG): : 317 - INOR
  • [38] TEMPERATURE, SOLVENT, AND SUBSTITUENT EFFECTS ON THE SINGLET OXIDATIONS OF ALLYLIC PHENYL SULFOXIDES, SULFONES, AND SULFIDES
    CLENNAN, EL
    CHEN, XN
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (21) : 8212 - 8218
  • [39] SELECTIVE DEALKYLATION OF ALKYL ARYL SULFIDES
    CABIDDU, S
    MELIS, S
    PIRAS, PP
    SOTGIU, F
    SYNTHESIS-STUTTGART, 1982, (07): : 583 - 584
  • [40] One-Pot Parallel Synthesis of Alkyl Sulfides, Sulfoxides, and Sulfones
    Bogolubsky, Andrey V.
    Moroz, Yurii S.
    Mykhailiuk, Pavel K.
    Ostapchuk, Eugeniy N.
    Rudnichenko, Alexander V.
    Dmytriv, Yurii V.
    Bondar, Anna N.
    Zaporozhets, Olga A.
    Pipko, Sergey E.
    Doroschuk, Roman A.
    Babichenko, Liudmyla N.
    Konovets, Anzhelika I.
    Tolmachev, Andrey
    ACS COMBINATORIAL SCIENCE, 2015, 17 (06) : 348 - 354