A novel catalytic decarbonylative Heck-type reaction and conjugate addition of aldehydes to unsaturated carbonyl compounds

被引：46

作者：

Yang, Luo ^{[1
]}

Correia, Camille A. ^{[1
]}

Guo, Xiangyu ^{[1
]}

Li, Chao-Jun ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 41期

基金：

加拿大自然科学与工程研究理事会;

关键词：

Decarbonylative coupling; Decarbonylative addition; Rhodium-catalyzed; Aldehyde; QUASI-NATURE CATALYSIS; BOND-FORMING REACTIONS; ALPHA-AMINO-ACIDS; ASYMMETRIC 1,4-ADDITION; ALPHA; BETA-UNSATURATED KETONES; DECARBOXYLATIVE PALLADATION; ARYLLEAD REAGENTS; RHODIUM; AIR; ARYLATION;

D O I：

10.1016/j.tetlet.2010.08.040

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel rhodium-catalyzed decarbonylative reaction of aldehydes with unsaturated carbonyl compounds was discovered to generate Heck-type reaction product and conjugate addition product. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：5486 / 5489

页数：4

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