A novel catalytic decarbonylative Heck-type reaction and conjugate addition of aldehydes to unsaturated carbonyl compounds

被引：46
|
作者：
Yang, Luo [1 ]
Correia, Camille A. [1 ]
Guo, Xiangyu [1 ]
Li, Chao-Jun [1 ]
机构：
[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada
来源：
TETRAHEDRON LETTERS | 2010年 / 51卷 / 41期
基金：
加拿大自然科学与工程研究理事会;
关键词：
Decarbonylative coupling; Decarbonylative addition; Rhodium-catalyzed; Aldehyde; QUASI-NATURE CATALYSIS; BOND-FORMING REACTIONS; ALPHA-AMINO-ACIDS; ASYMMETRIC 1,4-ADDITION; ALPHA; BETA-UNSATURATED KETONES; DECARBOXYLATIVE PALLADATION; ARYLLEAD REAGENTS; RHODIUM; AIR; ARYLATION;
D O I：
10.1016/j.tetlet.2010.08.040
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel rhodium-catalyzed decarbonylative reaction of aldehydes with unsaturated carbonyl compounds was discovered to generate Heck-type reaction product and conjugate addition product. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5486 / 5489
页数：4
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