Template-assisted assembly of porous lanthanide coordination polymers with 2-aminoterephthalic acid

被引：25
|
作者：
Liu, CB
Zheng, XJ
Yang, YY
Jin, LP [1 ]
机构：
[1] Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China
[2] Nanchang Univ, Dept Chem, Nanchang 330047, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 11期
关键词：
template; lanthanide; hydro- and solvothermal synthesis; 4,4 '-bipyridine; 2-aminoterephthalic acid;
D O I：
10.1016/j.inoche.2005.08.013
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Porous lanthanide coordination polymers, {[Ln(2)(atpt)(3)(H2O)(2)] 0.5(4,4'-bpy)(H2O)}(n) [Ln = Eu(1), Gd(2), Yb(3), H(2)atpt = 2-aminoterephthalic acid, 4,4'-bpy = 4,4'-bipyridine] were obtained by hydro-solvothermal reaction, in which 4,4'-bpy acts as template. For the first time the nitrogen atom of an atpt ligand coordinates to metal ions in 1-3. The photophysical properties and thermal stability of 1 were investigated. (c) 2005 Elsevier B.N. All rights reserved.
引用
收藏
页码：1045 / 1048
页数：4
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