Modeling and optimization of postpolymerization processes

被引:4
|
作者
Ilundain, P
Salazar, R
Alvarez, D
Da Cunha, L
Barandiaran, MJ
Asua, JM
机构
[1] Univ Basque Country, Fac Ciencias Quim, Dept Quim Aplicada, POLYMAT, San Sebastian, Spain
[2] Univ Basque Country, Fac Ciencias Quim, Dept Quim Aplicada, Grp Ingn Quim, San Sebastian, Spain
关键词
D O I
10.1021/ie030440+
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A mathematical model able to predict monomer removal and new volatile organic compound (VOC) formation during postpolymerization was developed. The model was validated in the postpolymerization of vinyl acetate (VAc) containing latexes. Then, the mathematical model was used to optimize postpolymerization processes. In the optimal process, the quantities of both VAc (<50 ppm) and new VOCs (<300 ppm) were substantially reduced.
引用
收藏
页码:1244 / 1250
页数:7
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