Syntheses, structure and magnetic properties of two vanadate garnets Ca5M4V6O24 (M=Co, Ni)

被引：16
|
作者：
Wang, Nannan [1 ,3 ]
He, Zhangzhen [1 ,2 ]
Cui, Meiyan [1 ]
Guo, Wenbin [1 ]
Zhang, Suyun [1 ]
Yang, Ming [1 ]
Tang, Yingying [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Peoples R China
[3] Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2015年 / 228卷
基金：
中国国家自然科学基金;
关键词：
Garnet; Vanadate; Crystal structure; Magnetic properties; SUBSTITUTIONS; SPECTRA;
D O I：
10.1016/j.jssc.2015.05.004
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two vanadate compounds Ca5M4V6O24 (M=Co, Ni) have been synthesized by a high-temperature solid-state reaction. The compounds are found to crystallize in the cubic system with a space group Ia-3d, which exhibit a typical garnet structural framework. Magnetic measurements show that Ca5M4V6O24 (M=Co, Ni) exhibit similar magnetic behaviors, in which Ca5Co4V6O24 possesses an antiferromagnetic ordering at T-N=K while Ca5Ni4V6O24 shows an antiferromagnetic ordering at T-N=similar to 7 K. (C) 2015 Elsevier Inc. All rights reserved.
引用
收藏
页码：245 / 249
页数：5
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