EFFICIENT AZIRIDINATION OF α,β-UNSATURATED KETONES WITH O-(2,4-DINITROPHENYL)-HYDROXYLAMINE

被引：7
|
作者：
Wang, Jin-jia [1 ]
Lao, Jin-hua [1 ]
Li, Xue-ming [1 ]
Lu, Rui-jiong [1 ]
Miao, Hui [1 ]
Yan, Ming [1 ]
机构：
[1] Sun Yat Sen Univ, Sch Pharmaceut Sci, Inst Drug Synth & Pharmaceut Proc, Guangzhou 510006, Guangdong, Peoples R China
来源：
SYNTHETIC COMMUNICATIONS | 2012年 / 42卷 / 11期
基金：
中国国家自然科学基金;
关键词：
Aziridination; O-(2,4-dinitrophenyl)-hydroxylamine; alpha; beta-unsaturated ketone; O-(DIPHENYLPHOSPHINYL)HYDROXYLAMINE; AMINATION;
D O I：
10.1080/00397911.2010.541968
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The aziridination of alpha,beta-unsaturated ketones with O-(2,4-dinitrophenyl)-hydroxylamine and tertiary amine was developed. trans-Aziridines were obtained exclusively in good yields. The reaction is proposed to occur via an aminimide intermediate.
引用
收藏
页码：1577 / 1584
页数：8
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