Ca(ii), Yb(ii) and Tm(iii) complexes with tri- and tetra-anions of 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene

被引：11
|
作者：
Fedushkin, Igor L. [1 ]
Lukina, Daria A. [1 ]
Skatova, Alexandra A. [1 ]
Lukoyanov, Anton N. [1 ]
Cherkasov, Anton V. [1 ]
机构：
[1] Russian Acad Sci, GA Razuvaev Inst Organomet Chem, Tropinina Str 49, Nizhnii Novgorod 603950, Russia
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 92期
关键词：
NAPHTHALENE COMPLEX; MOLECULAR-STRUCTURE; LITHIUM CATIONS; LIGAND; DIANION; CRYSTAL; METAL;
D O I：
10.1039/c8cc08108e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reduction of [(dpp-bian)M-2-(2+)(thf)(4)] (M = Ca, 1; Yb, 6; dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) by alkali metals results in heterometallic, [(dpp-bian)3-M2+K+(thf)(2)](2) (M = Ca, 2; Yb, 7), [(dpp-bian)(4-)Ca(2+)A(2)(+)(thf)(4)](2) (A = Na, 3; Li, 4; K, 5), [(dpp-bian)4-Yb2+K2+(thf)(4)](2) (8) and [(dpp-bian)(2)4-Yb32+K2+(thf)(8)] (9). The reduction of [(dpp-bian)TmBr(thf)(n)] (in situ) affords [(dpp-bian)4-Tm3+Na+(thf)](2) (10).
引用
收藏
页码：12950 / 12953
页数：4
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