Integrated infrared absorption coefficients of several partially fluorinated ether compounds:: CF3OCF2H, CF2HOCF2H, CH3OCF2CF2H, CH3OCF2CFClH, CH3CH2OCF2CF2H, CF3CH2OCF2CF2H AND CH2=CHCH2OCF2CF2H

被引：9
|
作者：
Heathfield, AE
Anastasi, C
McCulloch, A
Nicolaisen, FM
机构：
[1] Univ York, Dept Chem, York YO1 5DD, N Yorkshire, England
[2] ICI Chem & Polymers Div, Runcorn, Cheshire, England
[3] Univ Copenhagen, Inst Chem, DK-2100 Copenhagen, Denmark
来源：
ATMOSPHERIC ENVIRONMENT | 1998年 / 32卷 / 16期
关键词：
ethers; absorption; spectra; radiation; atmosphere; CFC's;
D O I：
10.1016/S1352-2310(97)00462-7
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The integrated absorption coefficients of CF3OCF2H, CF1HOCF2H, CH3OCF2CF2H, CH3OCF2CFClH, CH3CH2OCF2CF2H, CF3CH2OCF2CF2H and CH2 = CHCH2OCF2CF2H have been measured at 298 K for use in calculations of their global warming potentials. The results for the ethers were compared to the integrated absorption coefficients of a standard compound, CCl3F. To assess the potential impact of the ethers on terrestrial infrared radiation, the absorption coefficients were both weighted by the Plank function and also used in the simple method of estimating the instantaneous radiative forcing given in Pinnock et al. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2825 / 2833
页数：9
相关论文
共 50 条
  • [21] Atmospheric chemistry of CF3CFHCF2OCF3 and CF3CFHCF2OCF2H:: Reaction with Cl atoms and OH radicals, degradation mechanism, and global warming potentials
    Wallington, TJ
    Hurley, MD
    Nielsen, OJ
    Andersen, MPS
    JOURNAL OF PHYSICAL CHEMISTRY A, 2004, 108 (51): : 11333 - 11338
  • [22] Kinetic study of the reactions of Cl atoms with CF2CH2CH2OH, CF3CF2CH2OH, CHF2CF2CH2OH, and CF3CHFCF2CH2OH
    Papadimitriou, Vassileios C.
    Papanastasiou, Dimitrios K.
    Stefanopoulos, Vassileios G.
    Zaras, Aristotelis M.
    Lazarou, Yannis G.
    Papagiannakopoulos, Panos
    JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 111 (45): : 11608 - 11617
  • [23] Copper-Mediated -CF(OCF3)(CF2H) Transfer to Organic Electrophiles
    Ghaffari, Behnaz
    Porto, Luana L. T. N.
    Johnson, Nicole
    Ovens, Jeffrey S.
    Ehm, Christian
    Baker, R. Tom
    ACS ORGANIC & INORGANIC AU, 2024, 4 (06): : 628 - 639
  • [24] Measurement report: Radiative efficiencies of (CF3)2CFCN, CF3OCFCF2, and CF3OCF2CF3
    Trisna, Beni Adi
    Park, Seungnam
    Park, Injun
    Lee, Jeongsoon
    Lim, Jeong Sik
    ATMOSPHERIC CHEMISTRY AND PHYSICS, 2023, 23 (07) : 4489 - 4500
  • [25] Kinetics and Mechanisms of the Hydrogen Abstraction Reactions of CF3CF2CH2CH2F and CF3CH2CH2CF3 with Hydroxyl Radicals: Theoretical Studies
    Amiri, Ahmad
    Noorbala, Mohammad Reza
    Saheb, Vahid
    JOURNAL OF FLUORINE CHEMISTRY, 2019, 218 : 116 - 121
  • [26] Rate constants for the reactions of OH radicals with CF3OCF=CF2 and CF3CF=CF2
    Tokuhashi, K
    Takahashi, A
    Kaise, M
    Kondo, S
    Sekiya, A
    Fujimoto, E
    CHEMICAL PHYSICS LETTERS, 2000, 325 (1-3) : 189 - 195
  • [27] INFRARED MATRIX-ISOLATION STUDIES OF HYDROGEN-BONDS INVOLVING C-H BONDS - CF3H, (CF2H)2O AND CF3OCF2H WITH SELECTED BASES
    JENG, MLH
    AULT, BS
    JOURNAL OF MOLECULAR STRUCTURE, 1991, 246 (1-2) : 33 - 44
  • [28] Hydrogen-Atom Abstraction Reaction of CF3CH2OCF3 by Hydroxyl Radical
    Singh, Hari Ji
    Mishra, Bhupesh Kumar
    Rao, Pradeep Kumar
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2010, 31 (12) : 3718 - 3722
  • [29] Experimental and quantum chemical study of the reaction CF2+CH3⇆CF2CH3→CH2=CF2+H:: A key mechanism in the reaction between methane and fluorocarbons
    Yu, Hai
    Mackie, John C.
    Kennedy, Eric M.
    Dlugogorski, Bogdan Z.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (10) : 3758 - 3762
  • [30] INFRARED AND RAMAN SPECTRA OF CF3CH2I, CF3CH2BR, AND CF3CH2F
    EDGELL, WF
    WARD, C
    RIETHOF, TR
    JOURNAL OF MOLECULAR SPECTROSCOPY, 1963, 11 (02) : 92 - &
12345