Preparation and Properties of CT Complexes Derived from Verdazyl Radicals

被引:5
|
作者
Nakatsuji, Shin'ichi [1 ]
Kitamura, Akari [1 ]
Nishikawa, Kazuyoshi [2 ]
Morimoto, Yukio [2 ]
Yasuoka, Noritake [2 ]
Kawamura, Haruki [1 ]
Anzai, Hiroyuki [1 ]
机构
[1] Himeji Inst Technol, Dept Mat Sci, Kamigori, Hyogo 67812, Japan
[2] Himeji Inst Technol, Fac Sci, Dept Life Sci, Kamigori, Hyogo 67812, Japan
关键词
Verdazyl radicals; CT complexes; magnetic properties; X-ray analysis;
D O I
10.1080/10587259808044281
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The charge-transfer (CT) complexes of a series of 1,5-diphenyl-3-(p-substituted-phenyl)-verdazyl radicals with TCNQF4 or DDQ were prepared and their magnetic properties were investigated. The X-ray crystal structural analyses on the CT complexes consisted of 3-(4-methoxyphenyl)-, 3-(4-tolyl)-as well as 3-(4-chlorophenyl)-verdazyl radicals and TCNQF4 were carried out and correlated with their magnetic properties in which large decrease of magnetic susceptibility was observed in each complex.
引用
收藏
页码:235 / 240
页数:6
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